Analysis on Perturbation of Ground State Energy for Anharmonic Oscillator and Helium Atom

Abstract

This paper discusses some practical problems in quantum mechanics, particularly finding solutions of the Schrödinger equation for some cases, as it is a pivotal part of this area. The article focuses on using perturbation theory to calculate the approximate ground state energy for both helium atom and quartic anharmonic oscillator. For the helium atom, conventional perturbation theory is used to solve for the approximate energy, whilst for the anharmonic oscillator, a slightly different approach, that is perturbation theory incorporating a parameter, is chosen to improve the precision of the approximation. The final relative errors for the ground state energy of helium atom model are, for the first order perturbation, , and for the second order, , and that for the anharmonic oscillator is . The study of perturbation theory gives insights into understandings of how it may be modified further to pursue a better level of precision. This facilitates development of new approximation techniques for solving quantum-mechanical issues.